Bis(μ2-quinoline-2-carboxylato)-κ3 N,O 1:O 1;κ3 O 1:N,O 1-bis[(acetato-κO)(ethanol-κO)lead(II)]
نویسندگان
چکیده
In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl-ate group of the quinoline-2-carboxyl-ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa-hedral PbO(4)NE geometry (E is the electron lone pair). Two longer Pb⋯O inter-actions distort the geometry towards a Ψ-square-anti-prism. Inter-molecular O-H⋯O hydrogen bonds link the mol-ecules.
منابع مشابه
Bis(μ-quinoline-2-carboxylato)-κ3 N,O:O;κ3 O:N,O-bis[(acetato-κ2 O,O′)(methanol-κO)lead(II)]
The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated Pb(II) atom is chelated by the acetate anion as well as by the quinoline-2-carboxyl-ate anion. One O atom of the quinoline-2-carboxyl-ate anion bridges two symmetry-related Pb(II) atoms, forming the dinuclear compound. Aside from the six atoms connected to...
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متن کاملBis(μ-2-phenylquinoline-4-carboxylato)-κ3 O,O′:O;κ3 O:O,O′-bis[(2,2′-bipyridine-κ2 N,N′)(2-phenylquinoline-4-carboxylato-κ2 O,O′)cadmium(II)]
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011